PHYSICO-RHEOLOGICAL CHARACTERIZATION OF POLYMER MODIFIED BITUMEN
Keywords:
Temperature Susceptibility, Complex Modulus, Bitumen, Polymer, RheologyAbstract
The demand for better performing roads has encouraged the development of alternative materials to modify asphalt binders. This research carried out a physico-rheological characterization of polymer-modified bitumen. Styrene-butadiene-styrene (SBS), Polyethylene Terephthalate (PET) and Ethylene-vinyl Acetate (EVA) were used to partially replace bitumen in proportion of 10%, 20%, 30%, 40%, and 50%. The physical characterization was done by determining the Penetration Index (PI) of bitumen and polymer modified bitumen (PMB) according to Van Der Poel nomograph. Rheological properties of bitumen and PMB were investigated by performing a dynamic mechanical analysis (DMA) in accordance with ASTM D 7175-15. The PI result indicated that the PI of PET modified bitumen ranged between 0.07 and 2.38, SBS modified bitumen has PI values that ranged between 0.61 to 3.08 and EVA modified bitumen is characterized with PI values that ranged between 0.78 and 3.11. The DMA of bitumen and PMB showed that PMB has a very high complex modulus especially PET modified bitumen with the highest complex modulus of 5310 kPa at 30% partial replacement; this is an indication of high resistance to thermal and plastic deformation which is as a result of the formation of a tough, rigid, three-dimensional network. It can thus be concluded that PET, SBS and EVA are good modifiers of bitumen as they are capable of increasing specific properties of bitumen.
References
ASTM (2013). ASTM D 5 -13 - Standard Test Method for Penetration of Bituminous Materials. ASTM International, West Conshohocken, PA, 2013, www.astm.org.
ASTM (2014). ASTM D 36 / D 36M-14e1 - Standard Test Method for Softening Point of Bitumen (Ring-and-Ball Apparatus). ASTM International, West Conshohocken, PA, 2014, www.astm.org.
ASTM (2015). ASTM D 7175-15- Standard Test Method for Determining the Rheological Properties of Asphalt Binder Using a Dynamic Shear Rheometer. ASTM International, West Conshohocken, PA, 2014, www.astm.org
Chen J. S., Liao M. C. and Shiah M. S. (2002). Asphalt modified by styrene–butadiene–styrene triblock copolymer: Morphology and model. J Mater Civ Eng.; 14(3):224–5.
Kalantar Z. N., Mahrez A. and Karim M. R. (2010). Properties of bituminous binder modified with waste Polyethylene Terephthalate. Proceedings of Malaysian Universities Transportation Research Forum and Conferences. University Tenaga Nasional, Malaysia.
Mehmet Y. and Muhammed E. (2013). Effects of SBS and different natural asphalts on the properties of bituminous binders and mixtures. Construction and Building Materials, 44, 533 –540.
Ojeyemi M. Olabemiwo, Akintomiwa O. Esan, Hassan O. Bakare & Foluso O. Agunbiade (2017). Polymer modified-natural bitumen thermal aging resistance studies. International Journal of Pavement Engineering, DOI:10.1080/10298436.2017.1394102
Oyedepo O. J. and Olukanni E. O. (2015). Experimental investigation of the performance of palm kernel shell and periwinkle shell as partial replacement for coarse aggregate in asphaltic concrete. Journal of Building Materials and Structures, 2(1), 33-40.
Pink H. S., Merz R. E. and Bosniack D. S. (1980). Asphalt Rheology: Experimental Determination of Dynamic Moduli at Low Temperatures. Proceedings of the Association of Asphalt Technologists, 49, 64-77.
Polacco G., Berlincioni S., Biondi D. and Stastna J. (2005). Asphalt modification with different polyethylene-based polymers. Eur. Polym.; 41. 2831-13.
Navarro DomÃnguez F. J. and GarcÃa-Morales M. (2011). Polymer Modified Bitumen: Properties and Characterisation. Woodhead Publishing Series in Civil and Structural Engineering, 98-135
Read J. and Whiteoak D. (2003). The Shell Bitumen Handbook. Thomas Telford Ltd., London.
Robert N. H., Andy S. and John R. (2015). The Shell Bitumen Handbook, Sixth edition. ICE Publishing, London.
Van Der Poel C. (1954). A general system describing the visco-elastic properties of bitumens and its relation to routine test data. J Appl Chem; 4. 221-15.
Downloads
Published
Issue
Section
License
Copyright
With the submission of a manuscript, the corresponding author confirms that the manuscript is not under consideration by another journal. With the acceptance of a manuscript, the Journal reserves the exclusive right of publication and dissemination of the information contained in the article. The veracity of the paper and all the claims therein is solely the opinion of the authors not the journal.